Noble gas and halogen constraints on fluid sources in iron oxide-copper-gold mineralization: Mantoverde and La Candelaria,Northern Chile     

Robert Marschik  Mark A. Kendrick 《Mineralium Deposita》2015,50(3):357-371

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Factors contributing to a decadal oscillation in South African rainfall     

Mark R. Jury 《Theoretical and Applied Climatology》2015,120(1-2):227-237

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Analysing uncertainties in climate change impact assessment across sectors and scenarios     

Calum Brown  Evan Brown  Dave Murray-Rust  George Cojocaru  Cristina Savin  Mark Rounsevell 《Climatic change》2015,128(3-4):293-306

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Projected changes in diverse ecosystems from climate warming and biophysical drivers in northwest Alaska     

Mark Torre Jorgenson  Bruce G. Marcot  David K. Swanson  Janet C. Jorgenson  Anthony R. DeGange 《Climatic change》2015,130(2):131-144

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A conceptual framework of groundwater flow in some crystalline aquifers in Southeastern Ghana     

Sandow Mark Yidana  Samuel Ganyaglo  Bruce Banoeng-Yakubo  Thomas Akabzaa 《Journal of African Earth Sciences》2011,59(2-3):185-194

A conceptual groundwater flow model was developed for the crystalline aquifers in southeastern part of the Eastern region, Ghana. The objective was to determine approximate levels of groundwater recharge, estimate aquifer hydraulic parameters, and then test various scenarios of groundwater extraction under the current conditions of recharge. A steady state groundwater flow model has been calibrated against measured water levels of 19 wells in the area. The resulting recharge is estimated to range from 8.97 × 10^?5 m/d to 7.14 × 10^?4 m/d resulting in a basin wide average recharge of about 9.6% of total annual precipitation, which results in a basin wide quantitative recharge of about 2.4 million m³/d in the area. This compares to recharge estimated from the chloride mass balance of 7.6% of precipitation determined in this study. The general groundwater flow in the area has also been determined to conform to the general northeast–southwest structural grain of the country. The implication is that the general hydrogeology is controlled by post genetic structural entities imposed on the rocks to create ingresses for sufficient groundwater storage and transport. Calibrated aquifer hydraulic conductivities range between 0.99 m/d and over 19.4 m/d. There is a significant contribution of groundwater discharge to stream flow in the study area. Increasing groundwater extraction will have an effect on stream flow. This study finds that the current groundwater extraction levels represent only 0.17% of the annual recharge from precipitation, and that groundwater can sustain future increased groundwater demands from population growth and industrialization.  相似文献   

Biocalcification in the Eastern Oyster (<Emphasis Type="Italic">Crassostrea virginica)</Emphasis> in Relation to Long-term Trends in Chesapeake Bay pH     

George G. Waldbusser  Erin P. Voigt  Heather Bergschneider  Mark A. Green  Roger I. E. Newell 《Estuaries and Coasts》2011,34(2):221-231

Anthropogenic carbon dioxide (CO₂) emissions reduce pH of marine waters due to the absorption of atmospheric CO₂ and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed 23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures. Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the decrease in biocalcification.  相似文献   

Analytical model for screening potential CO<Subscript>2</Subscript> repositories     

Roland T. Okwen  Mark T. Stewart  Jeffrey A. Cunningham 《Computational Geosciences》2011,15(4):755-770

Assessing potential repositories for geologic sequestration of carbon dioxide using numerical models can be complicated, costly, and time-consuming, especially when faced with the challenge of selecting a repository from a multitude of potential repositories. This paper presents a set of simple analytical equations (model), based on the work of previous researchers, that could be used to evaluate the suitability of candidate repositories for subsurface sequestration of carbon dioxide. We considered the injection of carbon dioxide at a constant rate into a confined saline aquifer via a fully perforated vertical injection well. The validity of the analytical model was assessed via comparison with the TOUGH2 numerical model. The metrics used in comparing the two models include (1) spatial variations in formation pressure and (2) vertically integrated brine saturation profile. The analytical model and TOUGH2 show excellent agreement in their results when similar input conditions and assumptions are applied in both. The analytical model neglects capillary pressure and the pressure dependence of fluid properties. However, simulations in TOUGH2 indicate that little error is introduced by these simplifications. Sensitivity studies indicate that the agreement between the analytical model and TOUGH2 depends strongly on (1) the residual brine saturation, (2) the difference in density between carbon dioxide and resident brine (buoyancy), and (3) the relationship between relative permeability and brine saturation. The results achieved suggest that the analytical model is valid when the relationship between relative permeability and brine saturation is linear or quasi-linear and when the irreducible saturation of brine is zero or very small.  相似文献   

Making data useful for modelers to understand complex Earth systems   总被引：2，自引：1，他引：1  

Mark A. Parsons 《Earth Science Informatics》2011,4(4):197-223

The Arctic is changing rapidly with dramatic local and global effect. To understand that change requires understanding the Arctic as a system. Models of different processes and at various scales are necessary tools for analyzing and understanding the Earth system. Models are extremely diverse, yet they all require quality data. Through a series of case studies, augmented with ethnographic observation around the International Polar Year, this work examines how modelers assess, acquire, and prepare data for their models. By comparing specific case studies, common themes emerge that can be compared against broader observation. These themes, in turn, suggest data management techniques or requirements for data systems to improve access and use by modelers and generally improve understanding of the Arctic system. The study has an Arctic focus because of the rapid changes occurring in the Arctic, but the approach and results should apply generally to Earth system science. This case study based approach has proven to be a useful method for teasing out both general and specific data needs for different models. An overarching lesson is that greater short-term benefit to modelers and significant gains in efficiency can be achieved by improving the formats, convention, and consistency of the data rather than improved interfaces and analysis tools. A “data-first” philosophy can improve the data systems that support the overall interdisciplinary, integrative science necessary to understand the complex Earth system.  相似文献   

Carbonate cements in Miller field of the UK North Sea: a natural analog for mineral trapping in CO<Subscript>2</Subscript> geological storage     

Jiemin Lu  Mark Wilkinson  R. Stuart Haszeldine  Adrian J. Boyce 《Environmental Earth Sciences》2011,62(3):507-517

Miller field of the North Sea has had high concentrations of natural CO₂ for ~70 Ma. It is an ideal analog for the long-term fate of CO₂ during engineered storage, particularly for formation of carbonate minerals that permanently lock up CO₂ in solid form. The Brae Formation reservoir sandstone contains an unusually high quantity of calcite concretions; however, C and O stable isotopic signatures suggest that these are not related to the present-day CO₂ charge. Margins of the concretions are corroded, probably because of reduced pH due to CO₂ influx. Dispersed calcite cements are also present, some of which postdate the CO₂ charge and, therefore, are the products of mineral trapping. It is calculated that only a minority of the reservoired CO₂ in Miller (6–24%) has been sequestrated in carbonates, even after 70 Ma of CO₂ emplacement. Most of the CO₂ accumulation is dissolved in pore fluids. Therefore, in a reservoir similar to the Brae Formation, engineered CO₂ storage must rely on physical retention mechanisms because mineral trapping is both incomplete and slow.  相似文献   

Mineralogical and geochemical investigations of silicate-rich mine waste from a kyanite mine in central Virginia: implications for mine waste recycling   总被引：1，自引：1，他引：0  

Greg Geise  Erin LeGalley  Mark P. S. Krekeler 《Environmental Earth Sciences》2011,62(1):185-196

A kyanite mine in central Virginia produces a silicate-rich waste stream which accumulates at a rate of 450,000–600,000 tons per year. An estimated 27 million tons of this waste stream has accumulated over the past 60 years. Grain size distribution varies between 1.000 and 0.053 mm, and is commonly bimodal with modes typically being 0.425 and 0.250 mm and uniformity coefficients vary from 2.000 to 2.333. Hydraulic conductivity values vary from 0.017 to 0.047 cm/s. Mineralogy of the waste stream consists of quartz, muscovite, kyanite and hematite. Muscovite grains have distinct chemical compositions with significant Na₂O content (1.12–2.66 wt%), TiO₂ content (0.63–1.68 wt% TiO₂) and Fe content, expressed as Fe₂O₃ (up to 1.37 wt%). Major element compositions of samples were dominated by SiO₂ (87.894–90.997 wt%), Al₂O₃ (6.759–7.741 wt%), Fe₂O₃ (1.136–1.283 wt%), and K₂O (0.369–0.606 wt%) with other components being <1.000 wt%. Elements of environmental concern (V, Cr, Ni, Cu, Zn, As, Ag, Sn, Sb, Ba, Hg, Tl, and Pb) were detected; however, the concentrations of all elements except Ni were below that of the kyanite quartzites in the region from which the waste is derived. Both major and trace element compositions indicate minimal variation in composition. The waste stream has potential for recycling. Muscovite is suitable for recycling as a paint pigment or other industrial applications. Muscovite and hematite are commonly intergrown and are interpreted to be material where much of the elements of environmental concern are concentrated. Reprocessing of the waste stream to separate muscovite from other components may enable the waste stream to be used as constructed wetland media for Virginia and nearby states. Recycling of this mine waste may have a positive impact on the local economy of Buckingham County and aid in mitigation of wetland loss.  相似文献